Initially, the balance will tilt towards the iron block side because iron has a higher density than aluminum, resulting in a heavier block for the same volume. When 10.2g of mass is added to the aluminum side, the balance is restored, indicating that the weight difference between the iron and aluminum blocks is 10.2g. Since the volume is the same and the density of iron is known, we can calculate the volume using the mass difference and the densities of iron and aluminum.