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Question 12 An atom cap be modelled by electrons in 'orbit' around a small posi...
Jun 10, 2024
Solution
a
Use the de Broglie wavelength formula: λ=hmv\lambda = \frac{h}{mv} where λ\lambda is the wavelength, hh is Planck's constant, mm is the mass of the electron, and vv is the velocity of the electron. Given λ=314pm\lambda = 314 \, \mathrm{pm}, we can find the velocity vv
b
For an electron to form a stable orbit, the circumference of the orbit must be an integer multiple of the de Broglie wavelength. The circumference of the orbit is given by 2πr2\pi r. For r=100pmr = 100 \, \mathrm{pm}, the circumference is 2π×100pm=628pm2\pi \times 100 \, \mathrm{pm} = 628 \, \mathrm{pm}
c
Check if the circumference is an integer multiple of the de Broglie wavelength: 628pm314pm=2\frac{628 \, \mathrm{pm}}{314 \, \mathrm{pm}} = 2. Since 2 is an integer, the electron can form a stable orbit with a radius of 100 pm
Answer
Yes, the electron can form a stable orbit with a radius of 100 pm.
Key Concept
de Broglie Wavelength: The de Broglie wavelength of a particle is given by λ=hmv\lambda = \frac{h}{mv}, where hh is Planck's constant, mm is the mass of the particle, and vv is its velocity. For an electron to form a stable orbit, the circumference of the orbit must be an integer multiple of its de Broglie wavelength.
Explanation
Given the de Broglie wavelength of the electron and the radius of the orbit, we can determine if the orbit is stable by checking if the circumference of the orbit is an integer multiple of the de Broglie wavelength. In this case, it is, so the orbit is stable.
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