The boiling point of alkanes generally increases with molecular weight and branching. Among the given options, n-nonane (正壬烷) has the highest molecular weight, while 2,3-dimethylhexane (2,3-二甲基已烷) has the lowest due to its branching, leading to a lower boiling point compared to the others. Thus, 正壬烷 (n-nonane) has the lowest boiling point.