The catchment average rainfall over a 60 km^2 area would be expected to be smaller than the catchment average rainfall over a 100-hectare catchment, assuming uniform rainfall distribution, because the larger area would likely have more variation in rainfall.
The average rainfall over a catchment area is not solely dependent on the size of the catchment but also on the distribution of rainfall. However, in a larger catchment, there is a higher chance of variation in rainfall, which could lead to a lower average when compared to a smaller, more uniform area.